Synthesis of layered (2-D) V-based bimetallic oxalates from non-aqueous media that cannot be synthesized from aqueous media
citation_date
2006
Description
The reaction of (NBu4)3[VIII(ox)3] (1, ox = oxalate) and M(II) (M= Fe, Co, Ni, Cu) ions in MeCN, leads to the isolation of V-based coordination polymers of [N(n-Bu)4][FeIIVIII(ox)3]? 0.30{[N(n-Bu)4](BF4)} (2), [N(n-Bu)4][CoIIVIII(ox)3]?0.75{[N(n-Bu)4](BF4)} (3), [N(n-Bu)4][NiIIVIII(ox)3]?0.20{[N(n-Bu)4](BF4)}?0.20MeCN (4), and [N(n-Bu)4][CuIIVIII(ox)2](BF4)2 (5) composition.
Type
text;
citation_publisher
Royal Society of Chemistry
citation_firstpage
2463
Citation_lastpage
2467
citation_keywords
Magnetic; Coupling; Diffraction
citation_language
eng;
Bibliographic Citation
Min, K. S., & Miller, J. S. (2006). Synthesis of layered (2-D) V-based bimetallic oxalates from non-aqueous media that cannot be synthesized from aqueous media. Journal of the Chemical Society, Dalton, 2463-7.
