Electronic strengthening of graphene by charge doping

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Publication Type pre-print
School or College College of Engineering
Department Materials Science & Engineering
Creator Liu, Feng
Other Author Si, Chen; Duan, Wenhui; Liu, Zheng
Title Electronic strengthening of graphene by charge doping
Date 2012-01-01
Description Graphene is known as the strongest 2D material in nature, yet we show that moderate charge doping of either electrons or holes can further enhance its ideal strength by up to 17%, based on first-principles calculations. This unusual electronic enhancement, versus conventional structural enhancement, of the material's strength is achieved by an intriguing physical mechanism of charge doping counteracting the strain induced enhancement of the Kohn anomaly, which leads to an overall stiffening of the zone boundary K1 phonon mode whose softening under strain is responsible for graphene failure. Electrons and holes work in the same way due to the high electron-hole symmetry around the Dirac point of graphene, while overdoping may weaken the graphene by softening other phonon modes. Our findings uncover another fascinating property of graphene with broad implications in graphene-based electromechanical devices.
Type Text
Publisher American Physical Society
Volume 109
Issue 22
First Page 226802-1
Last Page 226802-5
Dissertation Institution University of Utah
Language eng
Bibliographic Citation Si, C., Duan, W., Liu, Z., & Liu, F. (2012). Electronic strengthening of graphene by charge doping. Physical Review Letters, 109(22), 226802-1-226802-5
Rights Management (c) American Physical Society http://dx.DOI: 10.1103/PhysRevLett.109.226802.
Format Medium application/pdf
Format Extent 1,008,527 bytes
Identifier uspace,18109
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Reference URL https://collections.lib.utah.edu/ark:/87278/s6708k7w